Photography of the shroud by Secondo Pia in 1898 indicated that the image resembled a photographic 'negative' and represents the first modern study.
The other method is “Relative Dating” which gives an order of events without giving an exact age (1): typically artefact typology or the study of the sequence of the evolution of fossils.
A form of radiometric dating used to determine the age of organic remains in ancient objects, such as archaeological specimens, on the basis of the half-life of carbon-14 and a comparison between the ratio of carbon-12 to carbon-14 in a sample of the remains to the known ratio in living organisms. A technique for measuring the age of organic remains based on the rate of decay of carbon 14.
The carbon 14 present in an organism at the time of its death decays at a steady rate, and so the age of the remains can be calculated from the amount of carbon 14 that is left. The cells of all living things contain carbon atoms that they take in from their environment.
Even for the first investigation, there was a possibility of using radiocarbon dating to determine the age of the linen from which the shroud was woven.
The size of the sample then required, however, was ~500cm, which would clearly have resulted in an unacceptable amount of damage, and it was not until the development in the 1970s of small gas-counters and accelerator-mass-spectrometry techniques (AMS), requiring samples of only a few square centimetres, that radiocarbon dating of the shroud became a real possibility. The shroud was separated from the backing cloth along its bottom left-hand edge and a strip (~10 mm x 70 mm) was cut from just above the place where a sample was previously removed in 1973 for examination.